Publikationen
2024
Reactivity Ratios of Biobased Dialkyl Itaconate Radical Polymerizations Derived from In-Line NMR Spectroscopy and Size-Exclusion Chromatography
M. Drache, B. A. Tameno Kouanwo, J. C. Namyslo, S. Pérocheau Arnaud, T. Robert, S. Beuermann
ACS Polymers Au 4, 540 (2024)
doi.org/10.1021/acspolymersau.4c00071
AI-based forecasting of polymer properties for high-temperature butyl acrylate polymerizations
J. Fiosina, P. Sievers, M. Drache, S. Beuermann
ACS Polymers AU4, 438 (2024)
doi.org/10.1021/acspolymersau.4c00047
Reverse Engineering of Vinyl Acetate Polymerizations by Genetic Algorithm-Based Multi-Objective Optimization
J. Fiosina, P. Sievers, M. Drache, S. Beuermann
Frontiers in Artificial Intelligence and Applications | Volume 392: ECAI 2024 - 27th European Conference on Artificial Intelligence, 19–24 October 2024, Santiago de Compostela, Spain – Including 13th Conference on Prestigious Applications of Intelligent Systems (PAIS 2024)
doi:10.3233/FAIA241068
Hydrophobic aerogels from vinyl polymers derived from radical polymerization: proof of concept
C. Adolfs, R. Altarabeen, L. Kimmritz, L. Gibowsky, B. Schroeter, S. Beuermann, I. Smirnova
Macromol. Rapid Commun. 45, 2400147 (2024)
doi.org/10.1002/marc.202400147
Reverse engineering of vinyl acetate polymerizations by genetic algorithm-based multi-objective optimization
J. Fiosina, P. Sievers, M. Drache, S. Beuermann
ChemRxiv 2024
doi.org/10.26434/chemrxiv-2024-kq3wd
Unexpected Stress Overshoot in Extensional Flow of Multi-arm Star Polymer Melts
Y. Wang, A. Goecke, V. Hirschberg, Y. Zhong, S. Liu, M. Wilhelm, Q. Huang
ACS Macro Letters, 812-817 (2024)
doi.org/10.1021/acsmacrolett.4c00182
Nonlinear Rheological Behavior of Glass-Forming Colloidal Suspensions under Oscillatory Shear: Experiment and Relation to Mode Coupling Theory Predictions
L. Fischer, M. Maier, N. Dingenouts, V. Hirschberg, A. Wittemann, M. Fuchs, M. Wilhelm
Journal of Rheology, 709-729 (2024)
doi.org/10.1122/8.0000827
Effect of mechanical recycling on the rheological and mechanical properties of bio-based and bio-degradable polybutylene succinate
J. Zhang, V. Hirschberg, M. Pollard, M. Wilhelm, D. Rodrigue
Resources, Conservation & Recycling, 107741 (2024)
doi.org/10.1016/j.resconrec.2024.107741
Elongational Rheology of 2, 3 and 4 Polymer Stars Connected by Linear Backbone Chains
V. Hirschberg, M.G. Schußmann, M.-C. Röpert, A. Goecke, M. Wilhelm, M.H. Wagner
Rheologica Acta, 1-16 (2024)
doi.org/10.1007/s00397-024-01455-x
Epoxy-Based Carbon Fiber-Reinforced Plastics Recycling via Solvolysis with Non-Oxidizing Methanesulfonic Acid
X. Zhang, R. Sibari, S. Chakraborty, S. Baz, G. T. Gresser, W. Benner, T. Brämer, L. Steuernagel, E. Ionescu, J. Deubener, S. Beuermann, G. Ziegmann, R. Wilhelm
Chem. Ing. Tech. 96, 987(2024)
doi.org/10.1002/cite.202300243
Predicting Maximum Strain Hardening Factor in Elongational Flow of Branched Pom-Pom Polymers from Polymer Architecture
M.G. Schußmann, M. Wilhelm, V. Hirschberg
Nature Communications, 15, 3545 (2024)
doi.org/10.1038/s41467-024-47782-8
IUPAC Recommended Experimental Methods and Data Evaluation Procedures for the Determination of Radical Copolymerization Reactivity Ratios from Composition Data
A. A. A. Autzen, S. Beuermann , M. Drache, C. M. Fellows, S. Harrisson, A. M. van Herk, R. A. Hutchinson, A. Kajiwara, D. J. Keddie, B. Klumperman, G. T. Russell
Polym. Chem., 15, 1851 (2024)
doi.org/10.1039/D4PY00270A
Temperature dependence of the number of defect-structures in poly(vinylidene fluoride)
J. Schwaderer, M. Drache, S. Beuermann
Molecules, 29, 1551 (2024)
doi.org/10.3390/molecules29071551
High performance thermoplastic elastomers of Polystyrene and Polyisoprene via the POM-POM topology
V. Hirschberg, M.G. Schußmann, M.-C. Röpert. N. Dingenouts, S. Bucheiser, H. Nirschl, M. Wilhelm
Macromolecules, (2024)
doi.org/10.1021/acs.macromol.3c02450.
Innovative reactor design for the preparation of polymer electrolyte membranes for vanadium flow batteries from pre-irradiation induced graft copolymerization of acrylic acid and AMPS on PVDF
M. Stehle, T. Lemmermann, F. Grasser, C. Adolfs, M. Drache, U. Gohs, A. Lohrengel, U. Kunz, S. Beuermann
J. Polym. Eng. 44, 233 (2024)
doi.org/10.1515/polyeng-2023-0216
Valorization of high-density polyethylene (HDPE) waste: Effect of mechanical recycling on the rheological properties
J. Zhang, V. Hirschberg, A. Goecke, M. Wilhelm, W. Yu, M. Orfgen, D. Rodigue
Polymer, 126866 (2024)
doi.org/10.1016/j.polymer.2024.126866
Monitoring of vanadium mass transfer using redox potential probes inside membranes during charge and discharge of flow batteries: An experimental study
T. Lemmermann, M. Becker, M. Stehle, M. Drache, S. Beuermann, U. Gohs, U. E.A. Fittschen, T. Turek, U. Kunz
J. Power Sources, 596, 233983 (2024)
doi.org/10.1016/j.jpowsour.2023.233983
Rheology of Poly(α-olefin) Bottlebrushes: Effect of Self-Dilution by Alkane Side Chains
M. Wagner, V. Hirschberg
Macromolecules, 57, 2110–2118 (2024)
doi.org/10.1021/acs.macromol.3c02430
Reverse Engineering of Radical Polymerizations by Multi-objective Optimization
J. Fiosina, P. Sievers, G. Kanagaraj, M. Drache, S. Beuermann
Polymers, 16, 945 (2024)
doi.org/10.3390/polym16070945
und
DOI: 10.20944/preprints202402.0199.v1
Fast and Scalable Synthetic Route to Densely Grafted, Branched Polystyrenes and Polydienes via Anionic Polymerization Utilizing P2VP as Branching Point
M. Schußmann, L. Kreuzer, V. Hirschberg
Macromolecular Rapid Communications, 2300674 (2024)
DOI: 10.1002/marc.202300674
2023
Macromolecular architecture-dependent polymorphous crystallization behavior of PVDF in the PVDF/γ-BL system via thermally induced phase separation
F. Gaßdorf, Z. Fan, J. Schwaderer, S. Beuermann, R. Wilhelm, A.P. Weber, M. Fischlschweiger
Macromol. Rapid Commun. 44, 2300177 (2023)
doi:10.1002/marc.202300177
Polymer Reaction Engineering meets Explainable Machine Learning
J. Fiosina, P. Sievers, M. Drache, S. Beuermann, ChemRxiv (2023)
doi: 10.26434/chemrxiv-2023-5vd8h
und
J. Fiosina, P. Sievers, M. Drache, S. Beuermann, Comput. Chem. Eng. 108356 (2023)
doi:10.1016/j.compchemeng.2023.108356
Influence of molecular characteristics and size effects in polystyrene pyrolysis
F. Gaßdorf, Z. Fan, J. Schwaderer, S. Beuermann, R. Wilhelm, A. Weber and Michael Fischlschweiger
Chem. Ing. Tech. 95, 1339 (2023)
doi:10.1002/cite.202300012
Kinetic Monte Carlo Simulations as a tool for unraveling the impact of solvent and temperature on polymer topology for self-initiated butyl acrylate radical polymerizations at high temperatures
J. Mätzig, M. Drache, G. Drache, S. Beuermann, Macromol. Theory Simul., eingeladener Artikel, 2300007 (2023)
doi:10.1002/mats.202300007
2022
Influence of the Solvent Evaporation Rate on the b-Phase Content of Electrosprayed PVDF Particles and Films Studied by a Fast Multi-Overtone QCM
J. Wiegmann, C. Leppin, A. Langhoff, J. Schwaderer, S. Beuermann, D. Johannsmann, A. P. Weber, Adv. Powder Technol. 33, 103452 (2022)
doi.org/10.1016/j.apt.2022.103452
Molecular weight as a key for electroactive phase formation in poly(vinylidene fluoride)
Z. Fan, M. Schwedes, S. Beuermann, M. Fischlschweiger, Mater. Res. Lett. 10, 271 (2022)
doi.org/10.1080/21663831.2022.2036840
Update and Critical Reanalysis of IUPAC Benchmark Propagation Rate Coefficient Data
S. Beuermann, S. Harrisson, R. A. Hutchinson, T. Junkers, G. T. Russell, Polym. Chem. 13, 1891 (2022)
doi.org/10.1039/D2PY00147K
In situ and in operando detection of redox reactions with integrated potential probes during vanadium transport in ion exchange membranes
T. Lemmermann, M. Becker, M. Stehle, M. Drache, S. Beuermann, M. S. Bogar, U. Gohs, U. E. A. Fittschen, T. Turek, U. Kunz, J. Power Sources 533, 231343 (2022)
doi.org/10.1016/j.jpowsour.2022.231343
Controlled Release of Tea Tree Oil from a Chitosan Matrix Containing Gold Nanoparticles
F. Matussek, A. Pavinatto, P. Knospe, S. Beuermann, R. C. Sanfelice, Polymers 14, 3808 (2022)
doi.org/10.3390/polym14183808
2021
Modeling complex semi-batch vinyl acetate polymerization processes
A. Feuerpfeil, M. Drache, L.-A. Jantke, T. Melchin, J. Rodríguez-Fernández, S. Beuermann, Ind. Eng. Chem. Res. 60, 18256 (2021)
doi.org/10.1021/acs.iecr.1c03114
Effects of supercritical carbon dioxide sorption on the microstructure of poly(vinylidene fluoride)
A. Zeinolebadi, J. Schwaderer, S. Beuermann, T. von Ostrowski, P. Jaeger, J. Supercrit. Fluids 177, 105347 (2021)
doi.org/10.1016/j.supflu.2021.105347
Self-initiated butyl acrylate polymerizations in bulk and in solution monitored by in-line techniques
J. Mätzig, M. Drache, S. Beuermann, Polymers13, 2021 (2021)
doi.org/10.3390/polym13122021
Ultrasonic degradation of polystyrene under different solvent and gas atmospheres for tailoring molecular mass and polydispersity of polystyrene fragments
J. Zimmermann, D. Kruppa, M. Fischlschweiger, S. Beuermann, S. Enders, Chem. Ing. Tech. 93, 289 (2021)
DOI:10.1002/cite.202000119
Influence of spray drying parameters on the formation of β-phase PVDF
J. Wiegmann, S. Beuermann, A. F. Weber, Chem. Ing. Tech.93(8), 1 (2021)
doi.org/10.1002/cite.202000194
Quantitative EPR study of poly(vinylidene fluoride) activated by electron beam treatment
M. S. Bogar, S. Beuermann, E. Dmitrieva, M. Drache, U. Gohs, U. Kunz, T. Lemmermann, M. Rosenkranz, M. Stehle, C. Zschech, Radiat. Phys. Chem. 184, 109421 (2021)
doi.org/10.1016/j.radphyschem.2021.109421
Determination of the through-plane profile of vanadium species in hydrated Nafion studied with micro X-ray absorption near-edge structure spectroscopy – proof of concept
C. Lutz, S. Hampel, S. Beuermann, T. Turek, U. Kunz, J. Garrevoet, G. Falkenberg, U. E. A. Fittschen, J. Synchrotron Radiat. 28, 1865 (2021)
Characterization of Dimeric Vanadium Uptake and Species in Nafion™ and Novel Membranes from Vanadium Redox Flow Batteries Electrolytes
C. Lutz, M. Breuckmann, S. Hampel, M. Kreyenschmidt, X. Ke, S. Beuermann, K. Schafner, T. Turek, U. Kunz, A. Guilherme Buzanich, M. Radtke, U. E. A. Fittschen, Membranes11, 576 (2021)
doi.org/10.3390/membranes11080576
Investigation on Vanadium Species Distribution in Nafion™ 117 after Cyclization in a Vanadium Redox Flow Battery
C. Lutz, S. Hampel, S. Beuermann, T. Turek, U. Kunz, A. Guilherme Buzanich, M. Radtke, U. E. A. Fittschen, Advances in X-ray Analysis, zur Veröffentlichung angenommen
Evidence for redox reactions during vanadium crossover inside the nanoscopic waterbody of Nafion 117 using XANES
C. Lutz, S. Hampel, X. Ke, S. Beuermann, T. Turek, U. Kunz, A. G. Buzanich, M. Radtke, U. E. A. Fittschen, J. Power Sources 483, 229176 (2021)
doi.org/10.1016/j.jpowsour.2020.229176
2020
Study of Langmuir and LS films of Poly(3-hexylthiophene) and Poly(vinylidene fluoride)
R. C. Sanfelice, D. Balogh, F. Lederle, J. Adams, S. Beuermann, J. Phys. Chem. B 124, 7037 (2020)
DOI:10.1021/acs.jpcb.0c02990
Inducing β phase crystallinity of PVDF homopolymer, blends and block copolymers by anti-solvent crystallization
F. Lederle, C. Härter, S. Beuermann, J. Fluorine Chem.234, 109522 (2020)
DOI:10.1016/j.jfluchem.2020.109522
Propagation kinetics of isoprene radical homopolymerization derived from pulsed laser initiated polymerizations
B. van Bueren, F. Brandl, S. Beuermann, Macromol. React. Eng. 14, 1900030 (2020)
DOI:10.1002/mren.201900030
Synthesis and characterization of azidated Adenopus breviflorus benth seed oil
E. T. Akintayo, C. O. Akintayo, I. O. Oluwayele, O. Ajaja, S. Beuermann, Green Chemistry Reviews and Letters13, 117 (2020)
DOI:10.1080/17518253.2020.1737251
Iodine Transfer emulsion polymerization of vinylidene fluoride
F. Brandl, J. Schwaderer, M. Drache, S. Beuermann, in "Opportunities for Fluoropolymers, Synthesis, Characterization, Processing, Simulation and Recycling", eds. B. Ameduri, S. Fomin, Elsevier, (2020)
2019
Identification of β scission products from free radical polymerizations of butyl acrylate at high temperature
M. Drache, M. Stehle, J. Mätzig, K. Brandl, M. Jungbluth, J. C. Namyslo, A. Schmidt, S. Beuermann, Polym. Chem. 10, 1956 (2019)
DOI: 10.1039/C9PY00103D
Polymer electrolyte membranes prepared by graft copolymerization of 2‒acrylamido‒2‒methylpropane sulfonic acid and acrylic acid on PVDF and ETFE activated by electron beam treatment
X. Ke, Y. Zhang, U. Gohs, M. Drache, S. Beuermann, Polymers 11, 1175 (2019)
DOI: 10.3390/polym11071175
Recycling of printed circuit boards employing supercritical carbon dioxide
K. Egerer, F. Brandl, N. Golzari, S. Beuermann
Scientific.net, Materials Science Forum 959, 100-106 (2019)
DOI: 10.4028/www.scientific.net/MSF.959.100
Critically evaluated propagation rate coefficients for radical polymerizations: acrylates and vinyl acetate in bulk (IUPAC Technical Report)
R. A. Hutchinson, S. Beuermann, Pure Appl. Chem. 91, 1883 (2019)
DOI: 10.1515/pac-2018-1108
2018
Preparation of polymer electrolyte membranes via radiation induced graft copolymerization on ETFE using the crosslinker N, N’-methylenebis(acrylamide)
X. Ke, M. Drache, U. Gohs, U. Kunz, S. Beuermann, Membranes 8, 102 (2018)
DOI: 10.3390/membranes8040102
Poly(meth)acrylate-PVDF core-shell particles from emulsion polymerization: preferential formation of the PVDF β crystal phase
F. Brandl, A. F. Thünemann, S. Beuermann, Polym. Chem. 9, 5359 (2018)
DOI: 10.1039/C8PY01236A
Kinetic Monte Carlo simulation based detailed understanding of the transfer processes in semi-batch iodine transfer emulsion polymerizations of vinylidene fluoride
F. Brandl, M. Drache, S. Beuermann, Polymers 10, 1008 (2018)
DOI: 10.3390/polym10091008
Ab initio Kinetic Monte Carlo Simulation of Seeded Emulsion Polymerizations of Styrene
M. Drache, K. Brandl, R. Reinhardt, S. Beuermann, Phys. Chem. Chem. Phys. 20, 10796 (2018)
DOI: 10.1039/C7CP07768H
Halbkontinuierliche Emulsionspolymerisation von Vinylidenfluorid
F. Brandl, S. Beuermann, Chem. Ing. Tech. 90, 1 (2018)
DOI: 10.1002/cite.201700089
2017
Inducing β phase crystallinity in block copolymers of vinylidene fluoride with methyl methacrylate or styrene
N. Golzari, J. Adams, S. Beuermann, Polymers 9, 306 (2017)
DOI: 10.3390/polym9080306
Propagation kinetics of isoprene - glycidyl methacrylate copolymerizations investigated via PLP-SEC
F. Brandl, M. Drache, J. E. S. Schier, T. Nentwig, D. Contreras-López, E. Saldívar-Guerra, R. A. Hutchinson, S. Beuermann, Macromol. Rapid Commun. 38, 1700105 (2017)
DOI: 10.1002/marc.201700105
Polymer electrolyte membranes prepared by pre-irradiation induced graft copolymerization on ETFE for vanadium redox flow battery applications
X. Li, A. R. dos Santos, M. Drache, X. Ke, U. Gohs, T. Turek, M. Becker, U. Kunz, S. Beuermann, J. Membr. Sci. 524, 419 (2017)
DOI: 10.1016/j.memsci.2016.10.053
Critically evaluated rate coefficients in radical polymerization - 8. Propagation rate coefficients for vinyl acetate in bulk
C. Barner-Kowollik, S. Beuermann, M. Buback, R. A. Hutchinson, T. Junkers, H. Kattner, B. Manders, A. N. Nikitin, G. T. Russell, A. M. van Herk, Macromol. Chem. Phys. 218, 1600357 (2017)
DOI: 10.1002/macp.201600357
2016
Experimentally calibrated random walk of branched polymers: a pragmatic approach
B. Hosemann, M. Drache, S. Beuermann, Macromol. Theory Simul. 25, 508 (2016)
DOI: 10.1002/mats.201600067
Advanced kinetic parameter fit applied to radical copolymerizations
B. Hosemann, M. Drache, S. Beuermann, Macromol. Symp. 370, 17 (2016)
Impact of rapid expansion of supercritical solution process conditions on the crystallinity of poly(vinylidene fluoride) nanoparticles
S. Wolff, S. Beuermann, M. Türk, J. Supercrit. Fluids 117, 18 (2016)
DOI: 10.1016/j.supflu.2016.07.013
Supercritical carbon dioxide as reaction medium for fluoropolymer synthesis and kinetic investigations into radical polymerization of VDF and HFP
B. Hosemann, R. Siegmann, S. Beuermann in "Fluorinated Polymers. From Fundamental to Practical Synthesis and Applications", B. Ameduri, H. Sawada (eds.), RSC Polymer Chemistry Series, 2016
ISBN: 978-1-78262-415-8
Low temperature ring-opening polymerization of diglycolide using organocatlysts with PEG as macroinitiator
V. Mawamba Kemo, C. Schmidt, Y. Zhang, S. Beuermann, Macromol. Chem. Phys. 217, 84 (2016)
DOI:10.1002/macp.201500491
Polymerelektrolytmembranen für Hoch- und Niedertemperatur-Brennstoffzellen aus strahlungsinduzierter Pfropfcopolymerisation
X. Li, M. Drache, U. Gohs, S. Beuermann, Chem. Ing. Tech. 88, 607 (2016)
DOI: 10.1002/cite.201500153
Fuel Cell Application of High Temperature Polymer Electrolyte Membranes Obtained by Graft Copolymerization of Acrylic Acid and 2-Hydroxyethylmethacrylate on ETFE Backbone Material
X. Li, M. Drache, X. Ke, U. Gohs, S. Beuermann, Macromol. Mater Eng. 301, 56 (2016)
DOI:10.1002/mame.201500207
2005 - 2015
Novel concept of polymer electrolyte membranes for high-temperature fuel cells based on ETFE grafted with neutral acrylic monomers
X. Li, M. Drache, U. Gohs, S. Beuermann, J. Membr. Sci. 495, 20 (2015)
DOI:10.1016/j.memsci.2015.07.056
Crystal Phase Transformation of ∝ into β phase poly(vinylidene fluoride) via particle formation caused by Rapid Expansion of Supercritical Solutions
S. Wolff, F. Jirasek, S. Beuermann, M. Türk, RSC Adv. 5, 66644 (2015)
DOI: 10.1039/C5RA12142F
Modeling of Branching Distributions in Butyl Acrylate Polymerization Applying Monte Carlo Methods
M. Drache, B. Hosemann, T. Laba, S. Beuermann, Macromol. Theory Simul. 24, 301 (2015)
DOI: 10.1002/mats.201400081
Fast Synthesis of High Molecular Weight Polyglycolide Using Diphenyl Bismuth Bromide as Catalyst
Y. Lu, C. Schmidt, S. Beuermann, Macromol. Chem. Phys. 216, 395 (2015)
DOI: 10.1002/macp.201400474
Aerosol Process for the In Situ Coating of Nanoparticles with a Polymer Shell
J. Poostforooshan, S. Rennecke, M. Gensch, S. Beuermann, G.-P. Brunotte, G. Ziegmann, A. P. Weber, Aerosol Science & Technology 48, 1111 (2014)
DOI:10.1080/02786826.2014.964354
Synthesis of high molecular weight polyglycolide in supercritical carbon dioxide
C. Schmidt, M. Behl, A. Lendlein, S. Beuermann, RSC Adv. 4, 35099 (2014)
DOI:10.1039/c4ra06815g (open access)
Detailed Copolymerization Propagation Kinetics of Homogeneous Phase VDF-HFP Copolymerizations in Supercritical CO2
R. Siegmann, M. Drache, S. Beuermann, J. Fluorine Chem. 159, 48 (2014)
DOI:10.1016/j.jfluchem.2014.01.002
Critically Evaluated Rate Coefficients in Radical Polymerization - 7. Secondary-Radical Propagation Rate Coefficients for Methyl Acrylate in Bulk
C. Barner-Kowollik, S. Beuermann, M. Buback, P. Castignolles, B. Charleux, M. L. Coote, R. A. Hutchinson, T. Junkers, I. Lacík, G. T. Russell, M. Stach, A. M. van Herk, Polym. Chem. 5, 204 (2014)
DOI: 10.1039/C3PY00774J (open access)
Propagation rate coefficients for vinylidene fluoride homopolymerizations
R. Siegmann, M. Drache, S. Beuermann, Macromolecules 46, 9507 (2013)
10.1021/ma401830a
Alkyne-azide coupling of tailored poly(vinylidene fluoride) and polystyrene for the synthesis of block copolymers
R. Vukićević, U. Schwadtke, S. Schmuecker, P. Schaefer, D. Kuckling, S. Beuermann, Polym. Chem.3, 409 (2012)
belongs to 10 most read articles in 12/2011; 10.1039/C1PY00427A
Investigations into Chain-Length-Dependent Termination in Bulk Radical Polymerization of 1H, 1H, 2H, 2H-Tridecafluorooctyl Methacrylate
J. Barth, R. Siegmann, S. Beuermann, G. T. Russell, M. Buback, Macromol. Chem. Phys.213, 19 (2012)
10.1002/macp.201100479
Propagation Rate Coefficients for Homogeneous Phase VDF - HFP Copolymerization in Supercritical CO2
R. Siegmann, E. Möller, S. Beuermann, Macromol. Rapid Commun.33, 1208 (2012)
10.1021/ma401830a
Poly(vinylidene fluoride)-functionalized single-wall carbon nanotubes for the preparation of composites with improved conductivity
R. Vukićević, I. Vukovic, H. Stoyanov, A. Korwitz, D. Pospiech, G. Kofod, K. Loos, G. ten Brinke, S. Beuermann, Polym. Chem.3, 2261 (2012)
10.1039/C2PY20166F
High Pressure Polymerization
S. Beuermann, M. Buback, in Comprehensive Polymer Science, K. Matyjaszewsky, M. Möller (eds.), Elsevier; 10.1016/B978-0-444-53349-4.00129-1
Simulating Controlled Radical Polymerizations with mcPolymer—A Monte Carlo Approach
M. Drache, G. Drache, Polymers4, 1416 (2012)
10.3390/polym4031416
Homogeneous Phase Copolymerizations of Vinylidene Fluoride and Hexafluoropropene in Supercritical Carbon Dioxide
E. Möller, S. Beuermann, Macromol. React. Eng. 5, 8 (2011)
invited article for series Enabling Technologies in Polymer Reaction Engineering
belongs to most accessed articles 1/2011-12/2011
10.1002/mren.201000031
Fullerenes decorated with poly(vinylidene fluoride)
R. Vukićević, S. Beuermann, Macromolecules44, 2597 (2011)
10.1021/ma102754c
1H,1H,2H,2H perfluorodecyl acrylate containing block copolymers from ARGET ATRP
U. Schreiber, B. Hosemann, S. Beuermann, Macromol. Chem. Phys. 212, 168 (2011)
10.1002/macp.201000307
Free Radical Copolymerization Kinetics of γ-Methyl-α-methylene-γ-butyrolactone (MeMBL)
R. A. Cockburn, R. Siegmann, K. A. Payne, S. Beuermann, T. F. L. McKenna, R. A. Hutchinson, Biomacromolecules 12, 2319 (2011)
10.1021/bm200400s
Towards the description and prediction of solvent induced variations in methacrylate propagation rate coefficients on the basis of solvatochromic parameters
A. Jeličić, Muttaqin, S. Beuermann, Macromol. React. Eng. 5, 232 (2011)
10.1002/mren.201000058
Block Copolymers of Poly(vinylidene fluoride) Obtained Via 1,3 Dipolar Cycloaddition
U. Schreiber, R. Vukićević, S. Beuermann, Polym. Prep. 52(2), 522 (2011)
Azide-terminated poly(vinylidene fluoride) as building block for nanocomposite materials and block copolymers
R. Vukićević, U. Schreiber, S. Beuermann, Polym. Prep. 52(2), 753 (2011)
Functionalization of carbon black nanoparticles with poly(vinylidene fluoride)
R. Vukićević, S. Hierzenberger, S. Hild, S. Beuermann, J. Polym. Sci., Polym. Chem. Ed. 48, 4847 (2010)
10.1002/pola.24277
Transparent, Flexible, and Paramagnetic Ionogels based on PMMA and the Ionic Liquid 1-butyl-3-methylimidazolium tetrachloroferrate(III) [Bmim][FeCl4]
Z.-L. Xie, A. Jeličić, F.-P. Wang, P. Rabu, A. Friedrich, S. Beuermann, A. Taubert, J. Mater. Chem.20, 9543 (2010)
10.1039/c0jm01733g
On the origin of ionic liquid induced variations in hydroxypropyl methacrylate propagation rate coefficients
A. Jeličić, F. Köhler, A. Winter, S. Beuermann, J. Polym. Sci.; Polym. Chem. Ed. 48, 3188 (2010)
10.1002/pola.24107
Individual rate coefficients for 1H,1H,2H,2H-tridecafluorooctyl methacrylate radical polymerizations
R. Siegmann, S. Beuermann, Macromolecules43, 3699 (2010)
Propagation and Termination Kinetics of PEGylated Methacrylate Radical Polymerizations
R. Siegmann, A. Jeličić, S. Beuermann, Macromol. Chem. Phys. 211, 546 (2010)
invited article
belongs to 12 most accessed articles in 2/2010
10.1021/ma902653b
In Line Spectroscopic Investigation of Fluorinated Copolymer Synthesis in Supercritical Carbon Dioxide
E. Möller, U. Schreiber, S. Beuermann, Macromol. Symp. 289, 52 (2010)
10.1002/masy.200900007
Prediction of the ionic liquid influence on propagation rate coefficients in methyl methacrylate radical polymerizations on the basis of Kamlet-Taft solvatochromic parameters
A. Jeličić, N. García, H.-G. Löhmannsröben, S. Beuermann, Macromolecules42, 8801 (2009)
10.1021/ma9017907
Propagation Rate Coefficient of Free-Radical Polymerization of Partially and Fully Ionized Methacrylic Acid in Aqueous Solution
I. Lacík, L. Učňová, S. Kukučková, M. Buback, P. Hesse, S. Beuermann, Macromolecules42, 7753 (2009)
10.1021/ma9013516
Iodine Transfer Radical Polymerizations of Vinylidene Fluoride in Supercritical Carbon Dioxide and Polymer Functionalization via Click Chemistry
M. Imran-ul-haq, N. Förster, R. Vukicevic, K. Herrmann, R. Siegmann, S. Beuermann, in: K. Matyjaszewski (Ed.), ACS Symposium Series, Vol. 1024 " Controlled/Living Radical Polymerization: Progress in RAFT, DT, NMP & OMRP ", p. 233, Washington DC, 200; 10.1021/bk-2009-1024.ch015
Influence of ionic liquid structure on the propagation kinetics of methyl methacrylate
A. Jeličić, S. Beuermann, N. García, Macromolecules42, 5062 (2009)
10.1021/ma900774e
Solvent influence on propagation kinetics in radical polymerizations studied by pulsed laser initiated polymerization
S. Beuermann, Macromol. Rapid Commun. 30, 1066 (2009)
10.1002/marc.200900131
invited Feature Article
Surprisingly high, bulk liquid-like mobility of silica-confined ionic liquids
R. Göbel, P. Hesemann, J. Weber, E. Möller, A. Friedrich, S. Beuermann, A. Taubert, Phys. Chem. Chem. Phys. 11, 3653 (2009)
10.1039/b821833a
Effect of chain transfer agents on kinetics and morphology of poly(vinylidene fluoride) synthesized in supercritical carbon dioxide
M. Imran-ul-haq, S. Beuermann, Macromol. Symp. 275/276, 102 (2009)
10.1002/masy.200950112
Effect of polymer properties on poly(vinylidene fluoride) particles produced by rapid expansion of CO2 + polymer mixtures
E. Breiniger, M. Imran-ul-haq, M. Türk, S. Beuermann, J. Supercrit. Fluids 48, 55 (2009)
10.1016/j.supflu.2008.09.016
Influence of polymer end groups on crystallization and morphology of poly(vinylidene fluoride) synthesized in homogeneous phase with supercritical carbon dioxide
S. Beuermann, M. Imran-ul-haq, B. Tiersch, Macromolecules 41, 7453 (2008)
10.1021/ma801325p
Termination kinetics of the free-radical polymerization of non-ionized methacrylic acid in aqueous solution
S. Beuermann, M. Buback, P. Hesse, R. A. Hutchinson, S. Kukučková, I. Lacík, Macromolecules41, 3513 (2008)
10.1021/ma7028902
Propagation Kinetics of Free-Radical Polymerizations in Ionic Liquids
I. Woecht, G. Schmidt-Naake,S. Beuermann, M. Buback, N. García, J. Polym. Sci. , Polym. Chem. Ed. 46, 1460 (2008)
10.1002/pola.22485
Living radical polymerizations of vinylidene fluoride in supercritical carbon dioxide
S. Beuermann, M. Imran-ul-haq, Polym. Prep. 49(2), 167 (2008)
Homogeneous phase polymerization of vinylidene fluoride in supercritical CO2: surfactant free synthesis and kinetics
S. Beuermann, M. Imran-ul-haq, Macromol. Symp. 259, 210 (2007)
Homogeneous Phase Polymerization of Vinylidene Fluoride in Supercritical Carbon Dioxide
S. Beuermann, M. Imran-ul-haq, J. Polym. Sci., Polym. Chem. Ed.45, 5626 (2007)
Critically evaluated rate coefficients for free-radical polymerization, 6, Propagation rate coefficient for methacrylic acid
S. Beuermann, M. Buback, P. Hesse, F.-D. Kuchta, I. Lacík, A. M. van Herk, Pure Appl. Chem.79, 1463 (2007)
Propagation rate coefficient of radical polymerization of non-ionized methacrylic acid in aqueous solution. The effect of monomer conversion
S. Beuermann, M. Buback, P. Hesse, S. Kukučková, I. Lacík, Macromol. Symp.248, 23 (2007)
Propagation Kinetics of Free-Radical Polymerization in Aqueous Solution
S. Beuermann, M. Buback, P. Hesse, S. Kukučková, I. Lacík, Macromol. Symp.248, 41 (2007)
Tubular reactor synthesis of styrene-methacrylate copolymers in solution with supercritical carbon dioxide
S. Beuermann, M. Buback, M. Gadermann,M. Jürgens, D. P. Saggu, J. Supercrit. Fluids39, 246 (2006)
Free-radical propagation rate coefficient of non-ionized methacrylic acid in aqueous solution from low monomer concentrations to bulk polymerization
S. Beuermann, M. Buback, P. Hesse, I. Lacík, Macromolecules39, 184 (2006)
Free-radical polymerization kinetics of 2-acrylamido-2-methyl-propane sulfonic acid in aqueous solution
S. Beuermann, M. Buback, P. Hesse, T. Junkers, I. Lacík, Macromolecules 39, 509 (2006)
RAFT Polymerization of Methyl Acrylate in Carbon Dioxide
T. Arita, S. Beuermann, M. Buback, P. Vana, Macromol. Mater. Eng. 290, 283 (2005)
Kinetics of Free-Radical Polymerization in Homogeneous Phase of scCO2
S. Beuermann, M. Buback, in M. F. Kemmere, T. Meyer (Eds.),
"Supercritical Carbon Dioxide in Polymer Reaction Engineering", Wiley-VCH, p. 55-80, 2005
1994 - 2004
Critically evaluated rate coefficients for free-radical polymerization, 5. Propagation rate coefficients for butyl acrylate
J. M. Asua, S. Beuermann, M. Buback, P. Castignolles, B. Charleux, R. G. Gilbert, R. A. Hutchinson, J. R. Leiza, A. N. Nikitin, J.-P. Vairon, A. M. van Herk, Macromol. Chem. Phys.205, 2151 (2004)
Influence of monomer structure on the propagation kinetics of acrylate and methacrylate homopolymerizations studied via PLP-SEC in fluid CO2
S. Beuermann, M. Buback, V. El Rezzi, M. Jürgens, D. Nelke, Macromol. Chem. Phys.205, 876 (2004)
PLP-SEC study into free-radical propagation rate coefficients of partially and fully ionized acrylic acid in aqueous solution
I. Lacík, S. Beuermann, M. Buback, Macromol. Chem. Phys. 205, 1080 (2004)
Rate coefficients of free-radical polymerization in homogeneous fluid mixtures with carbon dioxide
S. Beuermann, M. Buback, in: "Supercritical fluids as solvents and reaction media", G. Brunner (Hrsg.), Elsevier, p. 573, 2004
A Novel Approach to the Understanding of the Solvent Effects in Radical Polymerization Propagation Kinetics
S. Beuermann, N. García, Macromolecules37, 3018 (2004)
Impact of H-bonding on the propagation kinetics in butyl methacrylate radical polymerizations
S. Beuermann, Macromolecules37, 1037 (2004)
Continuous polymerizations of styrene, methyl methacrylate, and glycidyl methacrylate in homogeneous mixtures with supercritical carbon dioxide
S. Beuermann, M. Buback, M. Gadermann, M. Jürgens, F. Günzler, Macromol. Symp. 206, 229 (2004)
Solvation of poly(methyl acrylate) and poly(vinyl acetate) by CO2 studied via atomistic Monte Carlo simulation techniques
S. Beuermann, M. Buback, M. Drache, D. Nelke, G. Schmidt-Naake, e-polymers no. 002 (2004)
Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization of Styrene in Fluid CO2
T. Arita, S. Beuermann, M. Buback, P. Vana, e-polymers no. 003 (2004)
PLP-SEC Study into Free-Radical Propagation Rate of Non-Ionized Acrylic Acid in Aqueous Solution
I. Lacík, S. Beuermann, M. Buback, Macromolecules 36, 9355 (2003)
The influence of hydrogen bonding on the propagation rate coefficient in free-radical polymerizations of hydroxypropyl methacrylate
S. Beuermann, D. Nelke, Macromol. Chem. Phys. 204, 460 (2003)
Free-radical terpolymerization of styrene and two methacrylates in homogeneous phase containing supercritical CO2
S. Beuermann, M. Buback, M. Jürgens, Ind. Eng. Chem. Res.42, 6338 (2003)
Critically evaluated rate coefficients for free-radical polymerization, 4 Propagation rate coefficients for methacrylates with cyclic ester groups
S. Beuermann, M. Buback, T. P. Davis, N. García, R. G. Gilbert, R. A. Hutchinson, A. Kajiwara, I. Lacík, G. T. Russell, Macromol. Chem. Phys. 204, 1338 (2003)
Critically-evaluated propagation rate coefficients in free radical polymerizations - II. Methacrylates with cyclic ester groups
S. Beuermann, Pure & Appl. Chem. 75, 1091 (2003)
Rate coefficients of free-radical polymerization deduced from pulsed laser experiments
S. Beuermann, M. Buback, Prog. Polym. Sci.27, 191 (2002)
Propagation kinetics in free-radical polymerizations
S. Beuermann, Macromol. Symp.182, 31 (2002)
Pressure and Temperature Dependence of the Propagation Rate Coefficient of Free-Radical Styrene Polymerization in Supercritical Carbon Dioxide
S. Beuermann, M. Buback, C. Isemer, I. Lacík, A. Wahl, Macromolecules35, 3866 (2002)
Supercritical CO2 as a reaction medium for the homogeneous free-radical copolymerization of styrene and methacrylic acid esters
S. Beuermann, M. Buback, M. Gadermann, M. Jürgens, Chemical Engineering Transactions 2, 645 (2002)
High Pressure 'Living' Free-Radical Polymerization of Styrene in the presence of RAFT
M. J. Monteiro, R. Bussels, S. Beuermann, M. Buback, Aust. J. Chem. 55, 433 (2002)
Requirements Associated with Studies into a Chain-Length Dependence of Propagation Rate Coefficients via PLP-SEC Experiments
S. Beuermann, Macromolecules35, 9300 (2002)
Aqueous Phase Size-Exclusion-Chromatography Used for PLP-SEC Studies into Free-Radical Propagation Rate of Acrylic Acid in Aqueous Solution
I. Lacík, S. Beuermann, M. Buback, Macromolecules34, 6224 (2001)
Pressure dependence of the propagation rate coefficient kp for vinyl acetate polymerizations in bulk and in solution of fluid CO2
S. Beuermann, M. Buback, D. Nelke, Macromolecules34, 6637 (2001)
Critically evaluated rate coefficients for free-radical polymerization, 3. Propagation rate coefficients for alkyl methacrylates
S. Beuermann, M. Buback, T. P. Davis, R. G. Gilbert, R. A. Hutchinson, A. Kajiwara, B. Klumperman, G. T. Russell, Macromol. Chem. Phys. 201, 1355 (2000)
Homogeneous Free-Radical Polymerization of Styrene in Supercritical CO2
S. Beuermann, M. Buback, C. Isemer, A. Wahl, Macromol. Rapid Commun. 20, 26 (1999)
Free-Radical Polymerization in Reactive Supercritical Fluids
S. Beuermann, M. Buback, M. Busch, in P. G. Jessop, W. Leitner (Hrsg.),
"Chemical Synthesis using Supercritical Fluids", VCH, Weinheim, p. 326, 1999
Free-Radical Polymerization under High Pressure
S. Beuermann, M. Buback, in R. Winter (Hrsg.),
"High Pressure Molecular Science", Kluwer Academic Publishers, Dordrecht, p. 331, 1999
Termination Rate Coefficients of Butyl Acrylate Free-Radical Homopolymerization in Supercritical CO2 and in Bulk
S. Beuermann, M. Buback, C. Schmaltz, Ind. Eng. Chem. Res. 38, 3338 (1999)
Determination of Free-Radical Propagation Rate Coefficients for Methyl Methacrylate and n-Butyl Acrylate Homopolymerization in CO2
S. Beuermann, M. Buback, F.-D. Kuchta, C. Schmaltz, Macromol. Chem. Phys. 199, 1209 (1998)
Investigation of Methacrylate Free-Radical Depropagation Kinetics by Pulsed-Laser Polymerization
R. A. Hutchinson, D. A. Paquet, Jr, S. Beuermann, J. H. McMinn, Ind. Eng. Chem. Res. 37, 3567 (1998)
Critically-evaluated propagation rate coefficients in free radical polymerizations - II. Alkyl methacrylates
S. Beuermann, M. Buback, Pure & Appl. Chem.70, 1415 (1998)
Pressure and Temperature Dependence of Butyl Acrylate Propagation Rate Coefficients in Fluid CO2
S. Beuermann, M. Buback, C. Schmaltz, Macromolecules 31, 8069 (1998)
The Determination of Free-Radical Propagation Rate Coefficients for Cycloalkyl and Functional Methacrylates by Pulsed-Laser Polymerization
R. A. Hutchinson, S. Beuermann, D. A. Paquet, Jr., J. H. McMinn, C. Jackson, Macromolecules 31, 1542 (1998)
Pulsed Laser Experiments directed toward the detailed study of Free-Radical Polymerizations
S. Beuermann, M. Buback, in: ACS Symposium Series 685 Controlled Radical Polymerization , K. Matyjaszewski (Hrsg.), p. 84, ACS, Washington, DC, 1998
Free-Radical Polymerization Kinetics at High Pressure
S. Beuermann, M. Buback, High Pressure Research 15, 333 (1997)
Critically evaluated rate coefficients for free-radical polymerization, 2. Propagation rate coefficients for methyl methacrylate
S. Beuermann, M. Buback, T. P. Davis, R. G. Gilbert, R. A. Hutchinson, O. F. Olaj, G. T. Russell, J. Schweer, A. M. van Herk, Macromol. Chem. Phys.198, 1545 (1997)
A Pulsed-Laser Study of Penultimate Copolymerization Propagation Kinetics for Methyl Methacrylate / n-Butyl Acrylate
R. A. Hutchinson, J. H. McMinn, D. A. Paquet, Jr.; S. Beuermann, C. Jackson, Ind. Eng. Chem. Res. 36, 1103 (1997)
Propagation Kinetics of Methacrylic Acid Studied by Pulsed Laser Polymerization
S. Beuermann, D. A. Paquet, Jr.; J. H. McMinn, R. A. Hutchinson, Macromolecules30, 194 (1997)
The Determination of Free-Radical Propagation Rate Coefficients for Alkyl Methacrylates by Pulsed-Laser Polymerization
R. A. Hutchinson, S. Beuermann, D. A. Paquet, Jr., J. H. McMinn, Macromolecules 30, 3490 (1997)
Determination of Free-Radical Propagation Rate Coefficients of Butyl, 2-Ethylhexyl and Dodecyl Acrylates by Pulsed-Laser Polymerization
S. Beuermann, D. A. Paquet, Jr., J. H. McMinn, R. A. Hutchinson, Macromolecules29, 4206 (1996)
Effect of photoinitiator on the molar mass distribution obtained from a pulsed laser polymerization
U. Bergert, S. Beuermann, M. Buback, C. H. Kurz, G. T. Russell, C. Schmaltz, Macromol. Rapid Commun. 16, 425 (1995)
Kinetics of free radical solution polymerization of methyl methacrylate over an extended conversion range
S. Beuermann, M. Buback, G. T. Russell, Macromol. Chem. Phys.196, 2493 (1995)
The Application of Pulsed-Laser Methods for the Determination of Free-Radical Polymerization Rate Coefficients
R. A. Hutchinson, D. A. Paquet, Jr., J. H. McMinn, S. Beuermann, R. Fuller, C. Jackson, 5th International Workshop on Polymer Reaction Engineering (DECHEMA Monographs 131) ; VCH Publishers; 467, 1995
Rate of propagation in free radical polymerization of methyl methacrylate in solution
S. Beuermann, M. Buback, G. T. Russell, Maromol. Rapid Commun. 15, 647 (1994)
The pressure variation of the propagation rate coefficient for methyl methacrylate free radical polymerization
S. Beuermann, M. Buback, G. T. Russell, Maromol. Rapid Commun. 15, 351 (1994)